Name | triphenylphosphine-copper(I) hydride hexamer |
Synonyms | STRYKER'S REAGENT triphenylphosphane CUPROUS HYDRIDE TRIPHENYLPHOSPHINE HEXAMER HYDRIDO(TRIPHENYLPHOSPHINE)COPPER(I) HEXAMER TRIPHENYLPHOSPHINE-COPPER(I) HYDRIDE HEXAMER triphenylphosphine-copper(I) hydride hexamer hydrido(triphenylphosphine)copper(I) hexamer Cuprous hydride triphenylphosphine hexamer, Strykers reagent Cuprous hydride triphenylphosphine hexamer, Hydrido(triphenylphosphine)copper(I) hexamer, Strykers reagent, Triphenylphosphine-Copper(I) hydride Hexamer |
CAS | 33636-93-0 |
InChI | InChI=1/6C18H15P.6Cu.6H/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;;;;;;;/h6*1-15H;;;;;;;;;;;;/r6C18H15P.6CuH/c6*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;;;/h6*1-15H;6*1H |
Molecular Formula | C108H96Cu6P6 |
Molar Mass | 1961.04 |
Density | 1.367 |
Melting Point | 111° (dec) |
Appearance | Crystals |
Color | Red |
Storage Condition | Refrigerator (+4°C) |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
WGK Germany | 3 |
FLUKA BRAND F CODES | 10-21-36 |
HS Code | 29319090 |
Introduction | Stryker reagent [(Ph3P)CuH]6 For α,β-unsaturated carbonyl compounds, 1,4-reduction reaction can occur preferentially. Used with chiral bidentate ligands can catalyze asymmetric reduction. |